Appeared in: 2022 (3 sets)
(a) Illustrate the following reactions giving suitable example in each case :
(i) Gabriel phthalimide synthesis.
(ii) Carbylamine reaction.
(iii) Hoffmann bromamide degradation reaction.
OR
(b) Write the structures of A, B and C in the following reactions :
(i) $\text{CH}_3\text{CH}_2\text{Cl} \xrightarrow{\text{KCN}} \text{A} \xrightarrow{\text{LiAlH}_4} \text{B} \xrightarrow{\text{HNO}_2}{0 ^\circ\text{C}} \text{C}$
(ii) $\text{CH}_3\text{COOH} \xrightarrow{\text{NH}_3}{\Delta} \text{A} \xrightarrow{\text{(a) LiAlH}_4}{\text{(b) H}_2\text{O}} \text{B} \xrightarrow{\text{C}_6\text{H}_5\text{SO}_2\text{Cl}} \text{C}$