Chemistry Coordination Compounds 4 Marks
Appeared in: 2025 (3 sets)
The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity. Answer the following questions : (a) On the basis of CFT, explain why $[\text{Ti}(\text{H}_2\text{O})_6]\text{Cl}_3$ complex is coloured ? What happens on heating the complex $[\text{Ti}(\text{H}_2\text{O})_6]\text{Cl}_3$ ? Give reason. [Atomic no. : $\text{Ti} = 22$] (b) (i) What is crystal field splitting energy ? OR (b) (ii) On the basis of $\Delta_0$ and $\text{P}$ (pairing energy), how can you differentiate between a strong field ligand and a weak field ligand ? (c) Why are low spin tetrahedral complexes rarely observed ?