✓ 3 MARKS
Reasoning / Why
🔥 APPEARED IN 3 BOARD SETS
(a) When a coordination compound $ ext{CoCl}_3 \cdot 6 ext{NH}_3$ is mixed with excess of $ ext{AgNO}_3$ solution, 3 moles of $ ext{AgCl}$ are precipitated per mole of the compound. Write the structural formula of the complex, IUPAC name, its hybridisation and magnetic behaviour on the basis of valence bond theory.
OR
(b) (i) How many geometrical isomers are possible in each of the following complexes ?
(I) $[ ext{Cr}( ext{C}_2 ext{O}_4)_3]^{3-}$
(II) $[ ext{Co}( ext{NH}_3)_3 ext{Cl}_3]$
(ii) $[ ext{Co}( ext{NH}_3)_6]^{3+}$ is an inner orbital complex whereas $[ ext{Ni}( ext{NH}_3)_6]^{2+}$ is an outer orbital complex. Why ?
[Atomic number : $ ext{Co} = 27, ext{Ni} = 28$]
(iii) Write the formula of Wilkinson catalyst and its use.
01 // VERIFIED BOARD OCCURRENCES
| Year | Paper Code | Set | Position |
|---|---|---|---|
| CBSE 2026 | Series 56-4 | Set 1 | Question 25 |
| CBSE 2026 | Series 56-4 | Set 2 | Question 24 |
| CBSE 2026 | Series 56-4 | Set 3 | Question 26 |
02 // OFFICIAL CBSE MARKING SCHEME BREAKDOWN
- Step 1: Stating the fundamental formula / law statement (+1 Mark)
- Step 2: Intermediate mathematical substitution or proof steps (+1 Mark)
- Step 3: Correct final value or conclusion with mandatory SI units (+1 Mark)